Chemistry is traditionally divided into organic and inorganic chemistry. The former is the study of compounds containing at least one carbon-hydrogen bonds. 111974-74-4, Name is 11-(1-Piperazinyl)-dibenzo[b,f][1,4]thiazepine dihydrochloride, molecular formula is C17H19Cl2N3S, belongs to piperazines compound, is a common compound. In a patnet, author is Shintani, Takuji, once mentioned the new application about 111974-74-4, Recommanded Product: 111974-74-4.
Preparation of monoamine-incorporated polyamide nanofiltration membranes by interfacial polymerization for efficient separation of divalent anions from divalent cations
For the purpose of efficient separation of sulfate ions from magnesium ions, novel negatively-charged nanofiltration membranes were developed by incorporating the monoamines 4-aminobenozic acid, aniline-2,5-disulfonic acid monosodium salt, and iminodiacetic acid (IDA) during interfacial polymerization of piperazine (PIP) and trimesoyl chloride. PIP-amide membranes without these monomers tended to reject magnesium ions as well as sulfate ions. In contrast, incorporation of the monoamines resulted in large molecular weight cut-offs and large negative charge densities thanks to carboxyl or sulfo terminal groups of the monoamines, which enabled preferential permeation of magnesium ions while maintaining high rejection of sulfate ions. In particular, the IDA-incorporated nanofiltration membrane with an IDA to PIP + IDA mass ratio of 0.40 showed high rejection of sulfate ions with low rejection of magnesium ions even when the concentration of sodium chloride was much higher than that of magnesium sulfate. This result indicates the feasibility of the developed membrane for magnesium recovery from desalinated seawater in the electrodialysis process for table salt production.
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Reference:
Piperazine – Wikipedia,
,Piperazines – an overview | ScienceDirect Topics