Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 3400-55-3, is researched, SMILESS is CC(Br)C(OCC)OCC, Molecular C7H15BrO2Journal, Article, Journal of the American Chemical Society called Improving the Fatigue Resistance of Diarylethene Switches, Author is Herder, Martin; Schmidt, Bernd M.; Grubert, Lutz; Paetzel, Michael; Schwarz, Jutta; Hecht, Stefan, the main research direction is photochromism diarylethene derivative substituent structure.Application In Synthesis of 2-Bromopriopionaldehydediethylacetal.
When applying photochromic switches as functional units in light-responsive materials or devices, an often disregarded yet crucial property is their resistance to fatigue during photoisomerization. In the large family of diarylethene photoswitches, formation of an annulated isomer as a byproduct of the photochromic reaction turns out to prevent the desired high reversibility for many different derivatives To overcome this general problem, we have synthesized and thoroughly investigated the fatigue behavior of a series of diarylethenes, varying the nature of the hetaryl moieties, the bridging units, and the substituents. By anal. of photokinetic data, a quantification of the tendency for byproduct formation in terms of quantum yields could be achieved, and a strong dependency on the electronic properties of the substituents was observed In particular, substitution with 3,5-bis(trifluoromethyl)phenyl or 3,5-bis(pentafluorosulfanyl)phenyl groups strongly suppresses the byproduct formation and opens up a general strategy to construct highly fatigue-resistant diarylethene photochromic systems with a large structural flexibility.
There is still a lot of research devoted to this compound(SMILES:CC(Br)C(OCC)OCC)Application In Synthesis of 2-Bromopriopionaldehydediethylacetal, and with the development of science, more effects of this compound(3400-55-3) can be discovered.
Reference:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics