So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Canty, Allan J.; Dedieu, Alain; Jin, Hong; Milet, Anne; Richmond, Matthew K. researched the compound: Potassiumtris(1-pyrazolyl)borohydride( cas:18583-60-3 ).SDS of cas: 18583-60-3.They published the article 《Synthesis and Theoretical Studies of a Diorganohydridoplatinum(IV) Complex, PtHMe2{(pz)3BH-N,N’,N”} ([(pz)3BH]- = Tris(pyrazol-1-yl)borate)》 about this compound( cas:18583-60-3 ) in Organometallics. Keywords: platinum methyl hydrido pyrazolylborate complex preparation; SCF MP2 MO imine platinum dimethyl. We’ll tell you more about this compound (cas:18583-60-3).
The platinum(II) tris(pyrazol-1-yl)borate complex [PtMe2{(pz)3BH-N,N’}]- reacts with phenol or aqueous HBF4 in acetone to form the dimethylhydridoplatinum(IV) complex PtHMe2{(pz)3BH-N,N’,N”}. The complex decomposes above ∼140° in toluene-d8 to give methane. Theor. calculations at the SCF and MP2 levels for the species PtXMe2{(H2C:N-NH)3BH-N,N’,N”} (where X = H, OH, Me and the fragment [(H2C:N-NH)3BH]- is a model for [(pz)3BH]-) yield geometries that compare well with structural reports for Pt(OH)Me2{(pz)3BH} and PdMe3{(pz)3BH}.
From this literature《Synthesis and Theoretical Studies of a Diorganohydridoplatinum(IV) Complex, PtHMe2{(pz)3BH-N,N’,N”} ([(pz)3BH]- = Tris(pyrazol-1-yl)borate)》,we know some information about this compound(18583-60-3)SDS of cas: 18583-60-3, but this is not all information, there are many literatures related to this compound(18583-60-3).
Reference:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics