Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 18583-60-3, is researched, SMILESS is [BH-](N1N=CC=C1)(N2N=CC=C2)N3N=CC=C3.[K+], Molecular C9H10BKN6Journal, Article, Journal of the American Chemical Society called Metal-to-Metal Electron Transfer in Co/Fe Prussian Blue Molecular Analogues: The Ultimate Miniaturization, Author is Koumousi, Evangelia S.; Jeon, Ie-Rang; Gao, Qian; Dechambenoit, Pierre; Woodruff, Daniel N.; Merzeau, Pascal; Buisson, Lionel; Jia, Xiaolu; Li, Dongfeng; Volatron, Florence; Mathoniere, Corine; Clerac, Rodolphe, the main research direction is cobalt iron cyano pyrazolylborate heterodinuclear preparation structure electron transfer; Prussian Blue analog cobalt iron pyrazolylborate cyanido bridged heterodinuclear; crystal structure cobalt polypyridyl iron cyano pyrazolylborate heterodinuclear complex.Category: piperazines.
Co/Fe Prussian Blue analogs are known to display both thermally and light induced electron transfer attributed to the switching between diamagnetic {FeIILS(μ-CN)CoIIILS} and paramagnetic {FeIIILS(μ-CN)CoIIHS} pairs (LS = low spin; HS = high spin). A dinuclear cyanido-bridged Co/Fe complex, [{(Tp)Fe(CN)3}{Co(PY5Me2)}] (PY5Me2 = 2,6-bis(1,1-bis(2-pyridyl)ethyl)pyridine; Tp = hydridotris(pyrazol-1-yl)borate), the smallest {Fe(μ-CN)Co} moiety at the origin of the remarkable phys. properties of these systems, was designed by a rational building-block approach. Combined structural, spectroscopic, magnetic and photomagnetic studies reveal that a metal-to-metal electron transfer that can be triggered in solid state by light, temperature and solvent contents, is observed for the first time in a dinuclear complex.
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Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics