Recommanded Product: Potassiumtris(1-pyrazolyl)borohydride. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Potassiumtris(1-pyrazolyl)borohydride, is researched, Molecular C9H10BKN6, CAS is 18583-60-3, about Reactivity of an anionic Pd(ii) metallacycle with CH2X2 (X = Cl, Br, I): formal insertion of methylene into a Pd-Caryl bond. Author is Campora, Juan; Palma, Pilar; del Rio, Diego; Lopez, Jorge A.; Valerga, Pedro.
Whereas the reaction of the anionic palladium metalacycle [cyclic] [K{Pd(CH2CMe2-o-C6H4)(κ2-Tp)}] with CH2Cl2 leads to the isolation of the stable Pd(iv) chloromethyl complex [cyclic] [Pd(CH2CMe2-o-C6H4)(κ3-Tp)(CH2Cl)], the analogous reactions with CH2Br2 and CH2I2 give rise to the six membered metalacycles [cyclic] [Pd(CH2CMe2-o-C6H4(CH2))(κ3-Tp)X] (X = Br or I), as a result of the formal insertion of CH2 into the Pd-Caryl bond. The crystal structure of the bromomethyl complex was determined
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Piperazine – Wikipedia,
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