Tang, Meizhong; Han, Shuxiong; Huang, Shenglan; Huang, Shenlin; Xie, Lan-Gui published the article 《Carbosulfenylation of Alkenes with Organozinc Reagents and Dimethyl(methylthio)sulfonium Trifluoromethanesulfonate》. Keywords: alkene organozinc reagent dimethylmethylthiosulfonium trifluoromethanesulfonate carbosulfenylation; sulfide preparation.They researched the compound: 1-(Bromomethyl)-4-iodobenzene( cas:16004-15-2 ).Reference of 1-(Bromomethyl)-4-iodobenzene. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:16004-15-2) here.
The electrophilic alkylthiolation of alkenes, initiated by dimethyl(methylthio)sulfonium salts and the subsequent addition of various heteronucleophilies has been well-established. Regarding the use of carbon nucleophiles, however, only carefully designed sp-type carbon sources have been successfully applied. We herein present our findings on the methylthiolation of alkenes with dimethyl(methylthio)sulfonium trifluoromethanesulfonate, followed by carbon-carbon bond formation in the presence of organozinc reagents, thus achieving a catalyst-free protocol toward to the carbosulfenylation of alkenes.
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Reference:
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