Stauber, Julia M.; Qian, Elaine A.; Han, Yanxiao; Rheingold, Arnold L.; Kral, Petr; Fujita, Daishi; Spokoyny, Alexander M. published the article 《An organometallic strategy for assembling atomically precise hybrid nanomaterials》. Keywords: dodecaborane conjugate nanoparticle gold aminophosphine complex preparation thiolation; thioether conjugate dodecaborane preparation metalation gold aminophosphine.They researched the compound: 1-(Bromomethyl)-4-iodobenzene( cas:16004-15-2 ).Product Details of 16004-15-2. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:16004-15-2) here.
Metalation of hypercloso-dodecaborane-appended aryl iodide B12(OCH2C6H4I)12 with Au(I) Me-DalPhos (L) complex LAuCl gives rise to Au(III)-functionalized cage [B12[OCH2C6H4Au(Cl)(Me-DalPhos)]12][SbF6]11 (1), which was converted into thioethers [B12[OCH2C6H4SR]12]2- (2-20) by reaction with thiols RSH and used for further layer-by-layer nanocluster growth. For decades, chemists have striven to mimic the intricate design and diverse functions of naturally occurring systems through the bioinspired synthesis of programmable inorganic nanomaterials. The development of thiol-capped gold nanoparticles (AuNPs) has driven advancement in this area; however, although versatile and readily accessible, hybrid AuNPs are rarely atomically precise, which limits control over their surface topol. and therefore the study of complex structure-function relationships. Here, we present a bottom-up approach to the systematic assembly of atomically precise hybrid nanoclusters employing a strategy that mimics the synthetic ease with which thiol-capped AuNPs are normally constructed, while producing well-defined covalent nanoscale assemblies with diverse surface topologies. For the first time, using a structurally characterized cluster-based organometallic building block, we demonstrate the systematic synthesis of nanoclusters with multivalent binding capabilities to complex protein targets.
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