Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: (S)-Methyl 3-hydroxybutanoate, is researched, Molecular C5H10O3, CAS is 53562-86-0, about The role of acid in accelerating the asymmetric reduction of methyl acetoacetate with BINAP-chloro-(p-cymene)-Ru chloride complex.Category: piperazines.
The effect of addition of catalytic amounts of organic and inorganic acid on the asym. hydrogenation of Me acetoacetate with Ru-BINAP complex was studied. An increased activity was observed which was found to be dependent on the strength and the amount of acid added up to saturation It was proposed that the added acids protonate the carbonyl bond and hence facilitate the hydride transfer.
In some applications, this compound(53562-86-0)Category: piperazines is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.
Reference:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics