Synthetic Route of C7H15BrO2. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 2-Bromopriopionaldehydediethylacetal, is researched, Molecular C7H15BrO2, CAS is 3400-55-3, about (Alkylthio)bis(alkylsulfonyl)- and tris(alkylthio)propanes. Author is Boehme, H.; Russmann, H..
(RSO2)2C-Me Na+ (R = Me, Et), formed in situ from (RSO2)2CHMe and Na in dioxane, reacted with R1SCH2Cl (R1 = Me, Et) to give (RSO2)2CMeCH2SR1, oxidation of which gave (RSO2)2CMeCH2SO2R1. Reaction of (MeSO2)2C-H Na+ with MeSCH2Cl gave [(MeSO2)2CH]2CH2 and (MeSO2)2C(CH2SMe)2, which was oxidized to give (MeSO2)2C(CH2SO2Me)2. Condensation of MeSH with MeCOCH2SMeHCl and BrCHMeCH(OEt)2-HBr yielded (MeS)2CMeCH2SMe (I) and (MeS)2CHCHMeSMe (II), resp. A 3:2 I-II mixture was obtained by condensation of MeSH with MeOCH2COMe and HCl.
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Reference:
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