Efficient degradation of norfloxacin by carbonized polydopamine-decorated g-C3N4 activated peroxymonosulfate: Performance and mechanism was written by Deng, Yuqi;Liu, Shaobo;Liu, Yunguo;Tang, Yetao;Dai, Mingyang;Chen, Qiang;Wang, Huan. And the article was included in Chemosphere in 2022.Application In Synthesis of 1-Ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylic acid The following contents are mentioned in the article:
The use of metal-free graphite carbon nitride (CN) to activate peroxymonosulfate (PMS) has attracted extensive attention for organic pollutants degradation In this work, we prepared carbonized polydopamine-decorated g-C3N4 (CP-700) for activation of PMS to degrade norfloxacin (NOR). The CP-700 composite was obtained by using CN as a base material on which dopamine underwent an autopolymn. reaction to form a CN-PDA complex, followed by pyrolysis. The apparent porous structure and graphitization provided a large number of active sites for catalytic degradation, enabling CP-700 to exhibit excellent catalytic performance during PMS activation. The degradation of NOR was not hindered by sulfate radical (SO·-4) and hydroxyl radical (·OH). Singlet oxygen (1O2) and mediated electron transfer were ultimately identified as the primary mechanisms. According to the linear pos. correlation (R2 = 0.9922) between the semi-quant. carbonyl group (C=O) and the reaction rate constant, it was determined that the carbonyl group served as the important active site. The excellent electron transfer ability of CP-700 was evidenced by electrochem. techniques and the electron transfer pathway in the system was that PMS was adsorbed on the CP-700 surface to form metastable complex, and then the electron transfer between NOR and metastable complex was achieved. Based on the non-radical pathway, CP-700/PMS system showed a high tolerance to solution pH (3.0-11.0) and inorganic anions. The cyclic degradation experiments indicated that the system maintained a high degradation capability without the addition of addnl. CP-700, elucidating its potential application in the degradation of organic pollutants in the water. This study involved multiple reactions and reactants, such as 1-Ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylic acid (cas: 70458-96-7Application In Synthesis of 1-Ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylic acid).
1-Ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylic acid (cas: 70458-96-7) belongs to piperazine derivatives. Simple N-substituted piperazines have been found in many drug molecules. Although many piperazine derivatives occur naturally, piperazine itself can be synthesized by reacting alcoholic ammonia with 1,2-dichloroethane, by the action of sodium and ethylene glycol on ethylene diamine hydrochloride, or by reduction of pyrazine with sodium in ethanol.Application In Synthesis of 1-Ethyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydroquinoline-3-carboxylic acid
Referemce:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics