One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, such as the rate of change in the concentration of reactants or products with time. 106261-49-8, Name is 4-[(4-Methylpiperazin-1-yl)methyl]benzoic acid dihydrochloride, formurla is C13H20Cl2N2O2. In a document, author is Liu, Biming, introducing its new discovery. Application In Synthesis of 4-[(4-Methylpiperazin-1-yl)methyl]benzoic acid dihydrochloride.
Enhanced oxidative degradation of norfloxacin using peroxymonosulfate activated by oily sludge carbon-based nanoparticles CoFe2O4/OSC
In this study, oily sludge (OS) was pyrolyzed into an environmentally friendly OS carbon (OSC) material, which was used as the carrier of CoFe2O4 nanoparticles to prepare a heterogeneous catalyst CoFe2O4/OSC, and it was used to catalyze the degradation of norfloxacin (NFC) by peroxymonosulfate (PMS). X-ray diffraction (XRD) and transmission electron microscope (TEM) characterization results show that CoFe2O4/OSC had a spinel structure under high temperature pyrolysis conditions. The effects of initial pH, PMS dosage, catalyst dosage, and temperature on NFC degradation efficiency were also studied. Under a temperature of 25 degrees C, an initial pH of 7, a catalyst amount of 0.5 g/L, and a PMS dosage of 0.8 mM, the reaction rate constant reached 0.051 min(-1), and the degradation efficiency and total organic carbon of NFC reached 90.8% and 62%, respectively, within 60 min. Trace amounts of Co and Fe ions were leached from the system (both less than 30 mu g/L). After ten cycles, the degradation efficiency of NFC decreased to 69.8%. Radical quenching experiments, electron paramagnetic resonance, and X-ray fluorescence spectroscopy characterization proved that free-radical ((OH)-O-center dot, SO4 center dot-, and O-2(center dot-)) and nonradical (O-1(2)) active species were present in the system. Moreover, the CoFe2O4/OSC/PMS system involved the participation of two pairs of redox couples (Fe(II)/Fe(III) and Co(III)/Co(II)). Results from matrix-assisted laser desorption ionization time-of-flight mass spectrometry and ion chromatography proved that the main oxidation pathways of NFC were formed through the fragmentation of heterocycles, defluorination of benzene rings, decarboxylation reactions, and piperazine ring-opening process. At the same time, NFC was eventually oxidized to fluoride. This study provides potential for the resource utilization of OS and the application of sludge-type catalysts in PMS-activated oxidation systems.
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Reference:
Piperazine – Wikipedia,
,Piperazines – an overview | ScienceDirect Topics