Canty, Allan J.; Jin, Hong; Roberts, Andrew S.; Traill, Peter R.; Skelton, Brian W.; White, Allan H. published the article 《Synthetic and structural studies of methyl- and phenylpalladium(II) complexes of poly(pyrazol-1-yl)borates, and the η3-allylpalladium(II) complex Pd(η3-C3H5){(pz)3BH-N,N’}》. Keywords: crystal structure pyrazolylborate palladium complex; mol structure pyrazolylborate palladium complex; borate pyrazolyl palladium complex.They researched the compound: Potassiumtris(1-pyrazolyl)borohydride( cas:18583-60-3 ).Electric Literature of C9H10BKN6. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:18583-60-3) here.
The poly(pyrazol-1-yl)borate complexes PdMe{(pz)3BR-N,N’}(PPh3) (R = H, pz) are formed on the reaction of [PdMe(SMe2)(μ-I)]2 with K[(pz)3BR] in the presence of PPh3 and TlPF6, and the phenylpalladium(II) analogs are formed directly from PdIPh(tmeda) (tmeda = N,N,N’,N’-tetramethylethylenediamine) and K[(pz)3BR] in the presence of PPh3. X-ray diffraction studies of PdR{(pz)4B-N,N’}(PPh3) (R = Me, Ph) and PdPh{(pz)3BH-N,N’}(PPh3) reveal square planar geometry for Pd with the poly(pyrazol-1-yl)borate ligands in bidentate mode. The structure of Pd(η3-C3H5){(pz)3BH-N,N’} also was determined, and it contains a bidentate tris(pyrazol-1-yl)borate group with the η3-allyl group forming a dihedral angle of 125.5(2.1)° with the PdN2 plane. In both PdPh{(pz)3BH-N,N’}(PPh3) and Pd(η3-C3H5){(pz)3BH-N,N’} the uncoordinated pyrazole group lies above the coordination plane.
When you point to this article, it is believed that you are also very interested in this compound(18583-60-3)Electric Literature of C9H10BKN6 and due to space limitations, I can only present the most important information.
Reference:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics