COA of Formula: C5H13NO. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: (S)-1-(Dimethylamino)propan-2-ol, is researched, Molecular C5H13NO, CAS is 53636-17-2, about Enantioselective addition of diorganozincs to aldehydes catalyzed by β-amino alcohols. Author is Noyori, R.; Suga, S.; Kawai, K.; Okada, S.; Kitamura, M.; Oguni, N.; Hayashi, M.; Kaneko, T.; Matsuda, Y..
Nucleophilic addition of dialkylzincs to aldehydes in hydrocarbon solvents is markedly accelerated by the presence of a catalytic amount of a β-dialkylamino alc. Use of certain sterically constrained chiral amino alcs. such as 3-exo-(dimethylamino)isoborneol or 1-tert-butyl-2-piperidinoethanol effects highly enantioselective catalysis, giving secondary alcs. in up to 99% ee. Dimethyl-, diethyl-, di-n-butyl-, and di-n-pentylzincs have been employed for the alkylation of substituted benzaldehydes and some olefinic or aliphatic aldehydes. Configurational correlation between the chiral auxiliary and alkylation products is discussed.
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Reference:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics