Alyab’ev, S. B. et al. published their research in Izvestiya Vysshikh Uchebnykh Zavedenii, Khimiya i Khimicheskaya Tekhnologiya in 2007 | CAS: 611225-86-6

4-(4-Ethylpiperazin-1-ylmethyl)phenylamine (cas: 611225-86-6) belongs to piperazine derivatives. A form in which piperazine is commonly available industrially is as the hexahydrate, C4H10N2. 6H2O, which melts at 44 鎺矯 and boils at 125閳?30 鎺矯. Piperazines are very broad chemical group, covering a wide range of drugs from antidepressants to antihistamines. The connecting property of all these chemicals is the presence of a piperazine functional group.Category: piperazines

Synthesis of substituted 5-amino-3-aryl-4-(methoxycarbonyl)isoxazoles was written by Alyab’ev, S. B.;Kosul’nikova, T. S.;Dmitriev, D. E.;Il’in, A. P.;Kravchenko, D. V.;Filimonov, S. I.;Ivashchenko, A. V.. And the article was included in Izvestiya Vysshikh Uchebnykh Zavedenii, Khimiya i Khimicheskaya Tekhnologiya in 2007.Category: piperazines This article mentions the following:

A combinatorial library of substituted 5-amino-3-aryl-4-(methoxycarbonyl)isoxazoles was obtained by reaction of 3-aryl-4-methoxycarbonyl-5-chloroisoxazoles with primary and secondary amines in 1,4-dioxane in the presence of NEt3 under parallel synthesis conditions. Products were obtained in yields of 21-95%. This reaction proceeds less uniformly in DMF in the presence of K2CO3, and, in the case of primary amines, bis(4-methoxycarbonyl-3-aryl-isoxazol-5-yl)arylamines are also formed in 20-69% yields. In the experiment, the researchers used many compounds, for example, 4-(4-Ethylpiperazin-1-ylmethyl)phenylamine (cas: 611225-86-6Category: piperazines).

4-(4-Ethylpiperazin-1-ylmethyl)phenylamine (cas: 611225-86-6) belongs to piperazine derivatives. A form in which piperazine is commonly available industrially is as the hexahydrate, C4H10N2. 6H2O, which melts at 44 鎺矯 and boils at 125閳?30 鎺矯. Piperazines are very broad chemical group, covering a wide range of drugs from antidepressants to antihistamines. The connecting property of all these chemicals is the presence of a piperazine functional group.Category: piperazines

Referemce:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics

Chen, Yang et al. published their research in European Journal of Medicinal Chemistry in 2020 | CAS: 611225-86-6

4-(4-Ethylpiperazin-1-ylmethyl)phenylamine (cas: 611225-86-6) belongs to piperazine derivatives. Piperazine belongs to the family of medicines called anthelmintics. Piperazine and its salts did not induce point mutations in a bacterial test. A series of mutagenicity studies in cells, both in vitro and in vivo, has been completed and showed no evidence of mutagenic effect.Related Products of 611225-86-6

Discovery of new thieno[3,2-d]pyrimidine derivatives targeting EGFRL858R/T790M NSCLCs by the conformation constrained strategy was written by Chen, Yang;Yang, Linlin;Qiao, Hui;Cheng, Zhongyu;Xie, Jiahao;Zhou, Wenjuan;Huang, Xin;Jiang, Yaoxuan;Yu, Bin;Zhao, Wen. And the article was included in European Journal of Medicinal Chemistry in 2020.Related Products of 611225-86-6 This article mentions the following:

Studies on the third-generation of epidermal growth factor receptor tyrosine kinase inhibitors (EGFRTKIs) targeting EGFRL858R/T790M mutant remain hotspots, specifically for non-small cell lung cancer(NSCLC) were described. In the current study, a new series of EGFR-TKIs with thieno[3,2-d]pyrimidine derivatives bearing quinolin-2(1H)-ones I (R = 4-fluoro-phenylamino, 4-(4-methyl-piperazin-1-yl)-phenylamino, 4-morpholin-4-ylmethyl-phenylamino, etc.) was designed and synthesized, through conformational constrained strategy from the third generation of EGFR-TKI olmutinib. In vitro structure-activity relationship (SAR) studies indicated that compounds I (R = 4-(4-methyl-piperazin-1-yl)-phenylamino, 4-[1,4′]bipiperidinyl-1′-yl-3-fluoro-phenylamino, 4-(4-methyl-piperazin-1-ylmethyl)-phenylamino, 4-(4-ethyl-piperazin-1-ylmethyl)-phenylamino, 4-(2-(dimethylamino)ethylamino)-3-fluorophenylamino) exhibited good selective inhibition to EGFRL858R/T790M (IC50 閳?250 nM) over wild type EGFR (IC50 > 10000 nM). The observed selectivity of compounds I (R = 4-[1,4′]bipiperidinyl-1′-yl-3-fluoro-phenylamino, 4-(2-(dimethylamino)ethylamino)-3-fluorophenylamino) (A) was also proved by the computational mol. docking and the cellular thermal shift assay. These compounds I had good growth inhibitory effect on the four tested cancer cell lines. Specifically, I (R = 4-(2-(dimethylamino)ethylamino)-3-fluorophenylamino) could significantly inhibit the colony formation, wound healing and the expression of p-EGFR and its downstream p-ERK in EGFRL858R/T790M H1975 lung cancer cells. The above finding results suggest that the thieno[3,2-d]pyrimidine compounds, especially compounds A, can selectively target the mutant EGFRL858R/T790M in vitro and at cellular level and may serve as the lead compounds for generating new series of the third generation EGFR-TKIs. In the experiment, the researchers used many compounds, for example, 4-(4-Ethylpiperazin-1-ylmethyl)phenylamine (cas: 611225-86-6Related Products of 611225-86-6).

4-(4-Ethylpiperazin-1-ylmethyl)phenylamine (cas: 611225-86-6) belongs to piperazine derivatives. Piperazine belongs to the family of medicines called anthelmintics. Piperazine and its salts did not induce point mutations in a bacterial test. A series of mutagenicity studies in cells, both in vitro and in vivo, has been completed and showed no evidence of mutagenic effect.Related Products of 611225-86-6

Referemce:
Piperazine – Wikipedia,
Piperazines – an overview | ScienceDirect Topics

Simple exploration of 611225-86-6

The synthetic route of 611225-86-6 has been constantly updated, and we look forward to future research findings.

611225-86-6, 4-(4-Ethylpiperazin-1-ylmethyl)phenylamine is a piperazines compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated

611225-86-6, 104 mg (0.35 mMol) triphosgene are ^j-n’ ^ dissolved in13 ml ice-cooled CH2CI2. ^-/ ~~” Then a solution of 230 mg (1.05mMol) 4-(4-ethylpiperazin-1-O Hylmethyl)~aniline and 209 i (1.50 mMol) Et3N in 6 ml CH2CI2 is added during 8 min. After 3 additional minutes, the mixture is warmed up to rt by a water bath and then a solution of 1.0 mMol 5-(6-chloro-pyrimidin-4-yioxy)-2,3-dihydro-1H-indole (Step 14.1) and 139 jll. (1.00 mMol) Et3N in 6 ml CH2CI2 is added during 8 min. After 2 h at rt, the mixture is diluted with sat. Na2C03 solution / water 1:1 and EtOAc, the aqueous phase separated off and extracted twice with EtOAc. The organic layers are washed with water and brine, dried (Na2S04) and concentrated. Crystallization from DIPE gives the title compound: MS: [M+1]+= 493 / 495; TLC(CH2CI2/MeOH/NH3conc- 90:10:1): Rf = 0.24; HPLC: et_ = 10.5.

The synthetic route of 611225-86-6 has been constantly updated, and we look forward to future research findings.

Reference:
Patent; NOVARTIS AG; NOVARTIS PHARMA GMBH; WO2006/34833; (2006); A1;,
Piperazine – Wikipedia
Piperazines – an overview | ScienceDirect Topics

Simple exploration of 611225-86-6

The synthetic route of 611225-86-6 has been constantly updated, and we look forward to future research findings.

611225-86-6, 4-(4-Ethylpiperazin-1-ylmethyl)phenylamine is a piperazines compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated

611225-86-6, 104 mg (0.35 mMol) triphosgene are ^j-n’ ^ dissolved in13 ml ice-cooled CH2CI2. ^-/ ~~” Then a solution of 230 mg (1.05mMol) 4-(4-ethylpiperazin-1-O Hylmethyl)~aniline and 209 i (1.50 mMol) Et3N in 6 ml CH2CI2 is added during 8 min. After 3 additional minutes, the mixture is warmed up to rt by a water bath and then a solution of 1.0 mMol 5-(6-chloro-pyrimidin-4-yioxy)-2,3-dihydro-1H-indole (Step 14.1) and 139 jll. (1.00 mMol) Et3N in 6 ml CH2CI2 is added during 8 min. After 2 h at rt, the mixture is diluted with sat. Na2C03 solution / water 1:1 and EtOAc, the aqueous phase separated off and extracted twice with EtOAc. The organic layers are washed with water and brine, dried (Na2S04) and concentrated. Crystallization from DIPE gives the title compound: MS: [M+1]+= 493 / 495; TLC(CH2CI2/MeOH/NH3conc- 90:10:1): Rf = 0.24; HPLC: et_ = 10.5.

The synthetic route of 611225-86-6 has been constantly updated, and we look forward to future research findings.

Reference:
Patent; NOVARTIS AG; NOVARTIS PHARMA GMBH; WO2006/34833; (2006); A1;,
Piperazine – Wikipedia
Piperazines – an overview | ScienceDirect Topics

Brief introduction of 611225-86-6

As the paragraph descriping shows that 611225-86-6 is playing an increasingly important role.

611225-86-6, 4-(4-Ethylpiperazin-1-ylmethyl)phenylamine is a piperazines compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated

611225-86-6, General procedure: Compound 5 (1.0 eq.) and amine derivative (1.0 eq.) were dissolvedin dioxane (5 mL) and then Pd2(dba)3 (0.2 eq.), BINAP(0.2eq), Cesium carbonate (1.0eq.) were added. The reactionmixture was stirred at 100 C until the reaction was done. Theresultant mixture was concentrated, and the residue was purifiedby silica gel column chromatography to give the correspondingproducts 6a-r.

As the paragraph descriping shows that 611225-86-6 is playing an increasingly important role.

Reference:
Article; Chen, Yang; Cheng, Zhongyu; Huang, Xin; Jiang, Yaoxuan; Qiao, Hui; Xie, Jiahao; Yang, Linlin; Yu, Bin; Zhao, Wen; Zhou, Wenjuan; European Journal of Medicinal Chemistry; vol. 199; (2020);,
Piperazine – Wikipedia
Piperazines – an overview | ScienceDirect Topics

Downstream synthetic route of 611225-86-6

611225-86-6 4-(4-Ethylpiperazin-1-ylmethyl)phenylamine 1084996, apiperazines compound, is more and more widely used in various fields.

611225-86-6,611225-86-6, 4-(4-Ethylpiperazin-1-ylmethyl)phenylamine is a piperazines compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated

Step 3.Synthesis of 4-[(4-ethylpiperazinyl)methyl]benzeneisothiocyanate To 4-[(4-ethylpiperazinyl)methyl]phenylamine in acetone at 0 C. was added sodium bicarbonate (2 eq) and thiophosgene (2 eq).The mixture was brought to ambient temperature and concentrated and partitioned between ethyl acetate and water.The organic layer was dried with sodium bicarbonate and sodium sulfate and concentrated to yield 4-[(4-ethylpiperazinyl)methyl]benzeneisothiocyanate. MS: MH+=261.

611225-86-6 4-(4-Ethylpiperazin-1-ylmethyl)phenylamine 1084996, apiperazines compound, is more and more widely used in various fields.

Reference£º
Patent; Amiri, Payman; Fantl, Wendy; Levine, Barry Haskell; Poon, Daniel J.; Ramurthy, Savithri; Renhowe, Paul A.; Subramanian, Sharadha; Sung, Leonard; US2004/122237; (2004); A1;,
Piperazine – Wikipedia
Piperazines – an overview | ScienceDirect Topics

New learning discoveries about 611225-86-6

611225-86-6 4-(4-Ethylpiperazin-1-ylmethyl)phenylamine 1084996, apiperazines compound, is more and more widely used in various fields.

With the rapid development and complex challenges of chemical substances, new drug synthesis pathways are usually the most effective.611225-86-6,4-(4-Ethylpiperazin-1-ylmethyl)phenylamine,as a common compound, the synthetic route is as follows.,611225-86-6

4-((4-ethylpiperazin-1-yl)methyl)phenylamine(3.6g) was added to a solution of Compound 2-5(6.0g) in n-butanol(130ml). The mixture was reacted at 90C for 4.0 hours, cooled to room temperature, filtered, washed and dried to obtain a red solid in a yield of 81.8%. MS m/z(ESI): 426[M+H]+.

611225-86-6 4-(4-Ethylpiperazin-1-ylmethyl)phenylamine 1084996, apiperazines compound, is more and more widely used in various fields.

Reference£º
Patent; Si Chuan University; CSPC Zhongqi Pharmaceutical Technology (Shijiazhuang) Co., Ltd.; YANG, Shengyong; WEI, Yuquan; EP2578584; (2013); A1;,
Piperazine – Wikipedia
Piperazines – an overview | ScienceDirect Topics